Is the access key the same as the invoice number?
No. The invoice number (nNF) is just one of the 9 fields within the key, occupying positions 26 to 34. The full key combines that number with the state, date, CNPJ, model, series and other fields.
Why does the key have no letters, only digits?
Because every field is defined as numeric in the MOC layout, including the CNPJ (14 digits) and the state IBGE code. This simplifies both generation and reading by systems and barcodes/QR codes.
Can I tell the issuance date just by looking at the key?
Yes, partially: digits 3 through 6 (AAMM) give the year (2 digits) and the month, but not the exact day, which is not part of the access key.